Preparation of TiO2 nanostructures and its plasma coating in the Dye-Sensitized Solar Cell

Document Type : Original Article

Author

Department of Physics, Tafresh University, Tafresh, Iran

Abstract

In this research, TiO2 nanostructures were prepared using the hydrothermal method. The aerosol was regenerated from the precursor solution droplets by entering the non-thermal plasma and TiO2 nanostructures were deposited on the surface of the substrate. XRD and SEM analyses have been used to investigate nanostructure morphology. Dye-sensitized solar cells were fabricated using TiO2 nanostructures as a photoanode. The results showed that the surface prepared with TiO2 nanostructures by the hydrothermal method has a higher specific surface area, more pigment absorption, and short circuit current density than the unmodified surface. In addition, the TiO2 photoanode-based pigment solar cell using the hydrothermal method showed a short circuit current density of 21.67 mA/cm2, an open-circuit voltage of 0.67 V, and a photon-to-electricity conversion efficiency of 5.62%, which is about 17% more than the yield obtained. This comes from a solar cell without plasma modification with an efficiency of 5.11%. The increase in efficiency can be attributed to the increase in electrical conductivity in the photoanode, the tight connection of the conductive surface of the anode with the pigment molecules, and the greater contact surface of the photoanode with the electrolyte.

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References

[1] Salunkhe, R.R., Kaneti, Y.V. and Yamauchi, Y., 2017. Metal–organic framework-derived nanoporous metal oxides toward supercapacitor applications: progress and prospects. ACS nano, 11(6), pp.5293-5308.
[2] Denizalti, S., Ali, A.K., Ela, Ç., Ekmekci, M. and Erten-Ela, S., 2018. Dye-sensitized solar cells using ionic liquids as redox mediator. Chemical Physics Letters, 691, pp.373-378.
[3] Yang, M., Dong, B., Yang, X., Xiang, W., Ye, Z., Wang, E., Wan, L., Zhao, L., Wang, S., 2017. TiO2 nanoparticle/nanofiber-ZnO photoanode for the enhancement of the efficiency of dye-sensitized solar cells. RSC Advances, 7, p.41738-41744.
[4] Arof, A.K., Noor, I.M., Buraidah, M.H., Bandara, T.M.W.J., Careem, M.A., Albinsson, I. and Mellander, B.E., 2017. Polyacrylonitrile gel polymer electrolyte based dye sensitized solar cells for a prototype solar panel. Electrochimica Acta, 251, pp.223-234.
[5] Liu, R., Qiang, L.S., Yang, W.D. and Liu, H.Y., 2013. Enhanced conversion efficiency of dye-sensitized solar cells using Sm2O3–modified TiO2 nanotubes. Journal of power sources, 223, pp.254-258.
[6] Jung, H.G., Kang, Y.S. and Sun, Y.K., 2010. Anatase TiO2 spheres with high surface area and mesoporous structure via a hydrothermal process for dye-sensitized solar cells. Electrochimica Acta, 55(15), pp.4637-4641.
[7] Yang, J., Mei, S. and Ferreira, J.M.F., 2001. Hydrothermal synthesis of TiO2 nanopowders from tetraalkylammonium hydroxide peptized sols. Materials Science and Engineering: C, 15(1-2), pp.183-185.
[8] Gandhiraman, R.P., Jayan, V., Han, J.W., Chen, B., Koehne, J.E. and Meyyappan, M., 2014. Plasma jet printing of electronic materials on flexible and nonconformal objects. ACS applied materials & interfaces, 6(23), pp.20860-20867.
[9] Gandhiraman, R.P., Singh, E., Diaz-Cartagena, D.C., Nordlund, D., Koehne, J. and Meyyappan, M., 2016. Plasma jet printing for flexible substrates. Applied Physics Letters, 108(12).
[10] Tsumaki, M., Nitta, K., Jeon, S., Terashima, K. and Ito, T., 2018. Development of plasma-assisted inkjet printing and demonstration for direct printing of conductive silver line. Journal of Physics D: Applied Physics, 51(30), p.30LT01.
[11] Dey, A., Lopez, A., Filipič, G., Jayan, A., Nordlund, D., Koehne, J., Krishnamurthy, S., Gandhiraman, R.P. and Meyyappan, M., 2019. Plasma jet based in situ reduction of copper oxide in direct write printing. Journal of Vacuum Science & Technology B, 37(3).
[12] Dey, A., Krishnamurthy, S., Bowen, J., Nordlund, D., Meyyappan, M., 2018. Plasma Jet Printing and in Situ Reduction of Highly Acidic Graphene Oxide. ACS nano, 12, p.5473-81.
[13] Ramamurti, R., Gandhiraman, R.P., Lopez, A., Doshi, P., Nordlund, D., Kim, B. and Meyyappan, M., 2020. Atmospheric pressure plasma printing of nanomaterials for IoT applications. IEEE Open Journal of Nanotechnology, 1, pp.47-56.
[14] Bregadiolli, B.A., Fernandes, S.L. and Graeff, C.F.D.O., 2017. Easy and fast preparation of TiO2-based nanostructures using microwave assisted hydrothermal synthesis. Materials Research, 20(4), pp.912-919.
[15] Lou, B.S., Lai, C.H., Chu, T.P., Hsieh, J.H., Chen, C.M., Su, Y.M., Hou, C.W., Chou, P.Y. and Lee, J.W., 2019. Parameters affecting the antimicrobial properties of cold atmospheric plasma jet. Journal of Clinical Medicine, 8(11), p.1930.
[16] Liu, B.T. and Liou, J.Y., 2018. High efficiency of dye-sensitized solar cells with two-layer mesoporous photoanodes fabricated in a low temperature process. Electrochimica Acta, 261, pp.421-427.
[17] Xu, L., Xu, J., Hu, H., Cui, C., Ding, Z., Yan, Y., Lin, P. and
Wang, P., 2019. Hierarchical submicroflowers assembled from ultrathin anatase TiO2 nanosheets as light scattering centers in TiO2 photoanodes for dye-sensitized solar cells. Journal of Alloys and Compounds, 776, pp.1002-1008.
[18] Zhang, L., Cole, J.M., 2015. Anchoring Groups for DyeSensitized Solar Cells. ACS Applied Materials and Interfaces, 7, p.3427-3455.
[19] Mozaffari, S. and Nateghi, M.R., 2014. Effects of multi anchoring groups of catecholamine polymer dyes on the electrical characteristics of metal free dye-sensitized solar cells: A comparison study. Solar energy, 106, pp.63-71.
[20] Mozaffari, S., Dehghan, M., Borhanizarandi, M. and Nateghi, M.R., 2014. Effect of single-wall carbon nanotubes on the properties of polymeric gel electrolyte dye-sensitized solar cells. Journal of Solid State Electrochemistry, 18, pp.655-663.
[21] Lim, S.J., Kang, Y.S. and Kim, D.W., 2011. Dye-sensitized solar cells with quasi-solid-state cross-linked polymer electrolytes containing aluminum oxide. Electrochimica Acta, 56(5), pp.2031-2035.
Progress in Physics of Applied Materials
Volume 5, Issue 1
In progress
November 2025
Pages 11-16

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History

  • Receive Date: 15 September 2024
  • Revise Date: 09 October 2024
  • Accept Date: 16 October 2024

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