Synthesis ZnO/RGO nanocomposite: Structural characteristics and antifungal/antibacterial properties

Document Type : Short Communication and Letter

Authors

1 Department of Physics, Faculty of Science, Malayer University, Malayer, Iran.

2 Department of Biology, Faculty of Science, Malayer University, Malayer, Iran.

3 Department of Applied Chemistry, Faculty of Science, Malayer University, Malayer, Iran.

Abstract

The research presented herein involves the synthesis of ZnO nanoparticles (NPs) via a simple thermal treatment approach, utilizing a solution comprising Polyvinylpyrrolidone (PVP) as capping reagent and Zn nitrate as the metal source. Subsequently, these ZnO NPs underwent a conversion process into a ZnO/RGO nanocomposite (NCs) through a simple process of polymerization. Various characterization techniques such as Fourier transform infrared spectroscopy, field emission scanning electron microscopy and X-ray diffraction, were employed to investigate the phase composition, microstructure form, and degree of crystallinity. At room temperature, Analysis using Energy dispersive X-ray analysis confirmed the presence of C, Zn, and O elements in the prepared nanocomposite composition. Surface area of the ZnO/RGO NCs was determined through the adsorption–desorption isotherms of N2 gas using Brunauer–Emmett–Teller analysis. The antibacterial and antifungal activities of graphene, ZnO, and ZnO/RGO NCs with results from the disc agar diffusion method indicating the absence of antibacterial activity in graphene and ZnO NPs, while the ZnO/RGO nanocomposites displayed notable antifungal activity. Moreover, graphene alone did not exhibit any noticeable antifungal properties.

Keywords

Main Subjects


© 2024 The Author(s). Journal of Progress in Physics of Applied Materials published by Semnan University Press. This is an open access article under the CC-BY 4.0 license. (https://creativecommons.org/licenses/by/4.0/)

[1] Shih, K. Y., and Yu, S. C., 2021. Microwave-Assisted Rapid Synthesis of Eu (OH)3/RGO Nanocomposites and Enhancement of Their Antibacterial Activity against Escherichia coli. Materials, 15(1), 1-17.
[2] Choudhary, A. K., Gupta, A., Kumar, S., Kumar, P., Singh, R. P., Singh, P., and Kumar, V., 2020. Synthesis, Antimicrobial Activity, and Photocatalytic Performance of Ce Doped SnO2 Nanoparticles. Frontiers in Nanotechnology, 11.‏
[3] Haghniaz, R., Rabbani, A., Vajhadin, F., Khan, T., Kousar, R., Khan, A. R., and Wahid, F., 2021. Anti‐bacterial and wound healing‐promoting effects of zinc ferrite nanoparticles. Journal of Nanobiotechnology, 19(1), 1-15.‏
[4] Chireh, M., Karam, Z. M., Naseri, M., Jafarinejad-Farsangi, S., and Ghaedamini, H., 2022. Synthesis, characterization and cytotoxicity study of graphene/doped ZnO/SiO2 nanocomposites. Applied Physics A, 128(4), 1-8.‏
[5] Alamdari, S., SasaniGhamsari, M., Afarideh, H., Mohammadi, A., Geranmayeh, S., JafarTafreshi, M., Ehsani, M. H., Majles ara, M. H., 2019. Preparation and characterization of GO-ZnO nanocomposite for UV detection application. Optical Materials, 92 243-250.
[6] Ghasemi, R. Naseri, M. Souri, D. Kamalianfar, A., 2022. Structural and physical properties of Co1-xCdxFe2O4 /SiO2 nanocomposites, PPAM. 2 147-156.
[7] Chireh, M., Naseri, M., and Ghiasvand, S., 2019. Enhanced photocatalytic and antibacterial activities of RGO/LiFe5O8 nanocomposites. Journal of Photochemistry and Photobiology A: Chemistry, 385, 112063.‏
[8] Youssef, A. M., Abdel-Aziz, M. S., and El-Sayed, S. M., 2014. Chitosan nanocomposite films based on Ag-NP and Au-NP biosynthesis by Bacillus subtilis as packaging materials. International journal of biological macromolecules, 69, 185-191.‏
[9] Chireh, M., Naseri, M., and Kamalianfar, A., 2020. 57Fe Mossbauer spectroscopy investigation of NiFe2O4 and MnFe2O4 ferrite nanoparticles prepared by thermal treatment method. Applied Physics A, 126(7), 1-6.‏
[10] Chireh, M., and Naseri, M., 2019. Effect of calcination temperature on the physical properties of LiFe5O8 nanostructures. Advanced Powder Technology, 30(5), 952-960.‏
[11] Mohamed, M. B., Abdel‐Kader, M. H., and Alhazime, A. A., 2019. Structural and optical properties of doped ZnO/SiO2 nanocomposite. International Journal of Applied Ceramic Technology, 16(3), 1209-1217.
‏[12] Durmus, Z., Kurt, B. Z., and Durmus, A., 2019. Synthesis and characterization of graphene oxide/zinc oxide (GO/ZnO) nanocomposite and its utilization for photocatalytic degradation of basic fuchsin dye. ChemistrySelect, 4(1), 271-278.
‏[13] Alamdari, S., Ghamsari, M. S., Afarideh, H., Mohammadi, A., Geranmayeh, S., Tafreshi, M. J., and Ehsani, M. H., 2019. Preparation and characterization of GO-ZnO nanocomposite for UV detection application. Optical Materials, 92, 243-250.
‏[14] Sheshmani, S., and Nayebi, M., 2019. Modification of TiO2 with graphene oxide and reduced graphene oxide; enhancing photocatalytic activity of TiO2 for removal of remazol Black B. Polymer Composites, 40(1), 210-216.‏
[15] Mudila, H., Rana, S., and Zaidi, M. G. H., 2016. Electrochemical performance of zirconia/graphene oxide nanocomposites cathode designed for high power density supercapacitor. Journal of Analytical Science and Technology, 7(1), 1-11.‏
[16] Lin, Y., Dong, J., Dai, J., Wang, J., Yang, H., and Zong, H., 2017. Facile synthesis of flowerlike LiFe5O8 microspheres for electrochemical supercapacitors. Inorganic chemistry, 56(24), 14960-14967.‏
[17]Lili, H.,Yang, L.,Azlin ,M., Mengshi, L., 2011. Antifungal activity of zinc oxide nanoparticles against Botrytis cinerea and Penicillium expansum. Microbiological Research, 166( 3), 207-215.
[18] Hashemi, A., Tavafi, H., Naseri, M., Mojtabazadeh, H., abedi, M., tork, N., 2024. Structural and antibacterial properties of AgFe2O4, Fe3O4 nanoparticles and their nanocomposites. PPAM 4 (2024) 37-46.